Sky Sports will reveal two clashes involving Premier League heavyweights.
Liverpool will take on Arsenal at Anfield on Wednesday October 30 in a 7.30pm kick-off, whereas Chelsea will host Manchester United on exactly the same night (kick-off 8.05pm).
Both games will be aired live with another on Sky Sports Main Event along with one match on Sky Sports Football.
Chelsea will look to avenge their 4-0 defeat at Old Trafford on the beginning day of the entire year, although Liverpool will attempt to expand their unbeaten run against Arsenal.
Its a major attraction, two large teams and Im happy were in your home, said boss Frank Lampard after the Blues destiny was revealed. Man United will bring a powerful team .
If you want to win it, then you must beat the best, Solskjaer said following Manchester Uniteds penalty-shootout victory against Rochdale. We are likely to enjoy it and look ahead
Fixtures to be performed on Wednesday and Tuesday October 29 October 30
Everton vs Watford
Aston Villa vs Wolves
Manchester City vs Southampton
Burton vs Leicester
Crawley vs Colchester
Chelsea vs Manchester United – live on Sky Sports (station TBC)
Oxford vs Sunderland
Liverpool vs Arsenal – live on Sky Sports (station TBC)
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